A new zinc(II) supramolecular square: Synthesis, crystal structure, thermal behavior and luminescence
نویسندگان
چکیده
منابع مشابه
Synthesis and crystal structure of a new thiosemicarbzone, acenaphthenequinone thiosemicarbazone mono methanol
A new thiosemicarbzone compound was prepared by the reaction of acenaphthenequinone and thiosemicarbazide (1:1 molar ratio) in absolute methanol at 70°C. The crystal structure of this compound, acenaphthenequinone thiosemicarbazone mono methanol, was determined by X-ray crystallography. The unit cell parameters are as follows: a = 7.0384(14) Ǻ, b = 14.202(3) Ǻ, c = 14.270(3) Ǻ, β = 104.26(3)°. ...
متن کاملSolid–Solid Synthesis, Crystal Structure and Thermal Decomposition of Copper(II) Complex of 2-Picolinic Acid
The copper(II) complex [Cu(pic)2]·2H2O was synthesized with 2-picolinic acid (Hpic) and copper acetate as reactants by room temperature solid-solid reaction. The composition and structure of the complex was characterized by elemental analyses, single crystal X-ray diffraction, X-ray powder diffraction, FT-IR spectroscopy and thermogravimetry-differential scanning calor...
متن کاملCopper(I) thiocyanate-amine networks: synthesis, structure, and luminescence behavior.
A series of metal-organic networks of CuSCN were prepared by direct reactions with substituted pyridine and aliphatic amine ligands, L. Thiocyanate bridging is seen in all but 1 of 11 new X-ray structures. Structures are reported for (CuSCN)L sheets (L = 3-chloro- and 3-bromopyridine, N-methylmorpholine), ladders (L = 2-ethylpyridine, N-methylpiperidine), and chains (L = 2,4,6-collidine). X-ray...
متن کاملSYNTHESIS AND CRYSTAL STRUCTURE OF [Pph ] [WS (CUNCS) ] A. Taeb A. Beheshti and N.K. Javadi SYNTHESIS AND CRYSTAL STRUCTURE OF [Pph ] [WS (CUNCS) ]
The crystals of [WS (CuNCS) ] anion have been isolated from CH ,CI solution and examined by X-ray structural analysis as well as by IR spectroscopy. The unit cell is monoclinic with a= 14.3796(13), b= 18.039(1 I), c= 22.5956(23)& P= 96.053(8)', space group P2,/n (14), Z= 4. The crystal structure was refined by the least-squares calculations to a final R-value of 0.0398(Rw= 0.0443) for 2777 u...
متن کاملSynthesis, Characterization, and Crystal Structure Determination of a New Copper(II) Complex: [H2en][Cu(pydc)2].2H2O
The new complex of [H2en][Cu(pydc)2].2H2O (1) (where H2en and pydc are ethylenediammonium and 2,6-pyridinedicarboxylate, respectively) was synthesized by the reaction of a mixture of ethylenediamine (en) and 2,6-pyridinedicarboxylic acid (H2pydc) in a mixture of CH3OH/H2O as solvent. This complex was fully characterized by elemental analysis, IR, UV–Vis spectroscopy as well as single-crystal X-...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the Serbian Chemical Society
سال: 2015
ISSN: 0352-5139,1820-7421
DOI: 10.2298/jsc150204049w